Product ID:CROWN GASOLINE DRYER & ANTIFREEZE
MSDS Date:12/22/1987
FSC:6850
NIIN:00F014964
MSDS Number: BJVVT

R. H. CROWN CO., INC.

100 N. MARKET ST.
JOHNSTOWN, NY 12095

Emergency Phone: (518) 762-4589

Info Phone: (403) 527-8141

Cage: RHCRO

R. H. CROWN CO., INC.

JOHNSTOWN, NY 12095

Telephone: (518) 762-4589

Cage: RHCRO

METHYL ALCOHOL (METHANOL) (SARA III)

CAS: 67-56-1

RTECS: PC1400000

Fraction By Weight: 99.85%

OSHA PEL S,200PPM/250STEL

ACGIH TLV: S,200PPM/250STEL; 93

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

LD50 LC50 Mixture:ORAL LD50 (RAT): 13,000 MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:SKIN: REDNESS. EYE: IRRITATION,
TEARING, & BURNING. INHALATION: IRRITATION OF MUCOUS MEMBRANE,
HEADACHE, SLEEPINESS, NAUSEA, GIDDINESS, & LOSS OF CONSCIOUSNESS.
INGESTION: POISONOUS, NAUSEA, HEADACHE, VISUAL DISTURBANCES
RANGING FROM DOUBLE VISION TO BLINDNESS.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:SKIN: IRRITATION, DRYNESS, & CRACKING.
INHALATION: SYSTEMIC POISONING, IMPAIRED VISION, & BLINDNESS. EYES:
IRRITATION, TEARING, & BURNING. INGESTION: POISONIOUS, NAUSEA,
HEADACHE, VISUAL DISTURBANCES RANGING FROM DOUBLE VISION TO
BLINDNESS.
Medical Cond Aggravated by Exposure:EMPHYSEMA & BRONCHITIS.

First Aid:EYES: FLUSH W/PLENTY OF WATER FOR AT LEAST 15 MINS. SKIN:
WASH UNDER SHOWER W/SOAP & WATER. INHALATION: REMOVE TO FRESH AIR.
GIVE CPR OR OXYGEN IF NEEDED. INGESTION: IF CONSCIOUS, GIVE LARGE
AMOUNTS O F WATER OR MILK. INDUCE VOMITING. OBTAIN MEDICAL
ATTENTION IN ALL CASES.

Flash Point:52F
Lower Limits:6%
Upper Limits:36%
Extinguishing Media:WATER (4:1), PURPLE K DRY CHEMICAL POWDER, AQUEOUS
FILM FORMING FOAM ALCOHOL RESISTANT W/6% FOAM EQUIPMENT, OR CO2.
Fire Fighting Procedures:WATER MAY BE INEFFECTIVE. USE FINE WATER/FOG
TO CONTROL FIRE SPREAD/COOL STRUCTURES/CONTAINERS. WEAR FULL FACE,
POSITIVE PRESSURE, SCBA & PROTECTIVE CLOTHING.
Unusual Fire/Explosion Hazard:AUTOIGNITION TEMP: 725F.

Spill Release Procedures:ELIMINATE ALL IGNITION SOURCES. STOP SPILL &
USE ABSORBENT MATERIALS. CONTAIN BY DIKING. RECOVER METHANOL OR
DILUTE W/WATER TO REDUCE FIRE HAZARD. PREVENT IT FROM ENTERING
SEWER, DRAINS, & WATERWAYS. EVACUATE AREA. WEAR SCBA & PROTECTIVE
CLOTHING.

Handling and Storage Precautions:NO SMOKING OR OPEN FLAME IN STORAGE,
HANDLING AREAS. USE EXPLOSION PROOF EQUIPMENT. ENSURE PROPER
ELECTRICAL GROUNDING PROCEDURES ARE IN PLACE.
Other Precautions:AVOID NATURAL RUBBERS, USE NEOPRENE. GASKETS SHOULD
BE FLEXITALLIC SPIRALLY WOUND STAINLESS STEEL W/ASBESTOS. STORE IN
TOTALLY ENCLOSED EQUIPMENT, DESIGNED TO AVOID HUMAN CONTACT. TANKS
MUST BE GROUND ED, VENTED, NITROGEN BLANKETED, & DIKED.

Respiratory Protection:NIOSH APPROVED RESPIRATOR
Ventilation:LOCAL EXHAUST/MECHANICAL VENTILATION TO KEEP DESIGNED ACCORDING TO APPROVED ENVIRONMENTAL ENGINEERING STANDARD.
Protective Gloves:CHEMICAL RESISTANT
Eye Protection:FACE SHIELD/SAFETY GLASSES W/SIDE SHIELD
Other Protective Equipment:CHEMICAL RESISTANT FOOTWEAR, PANTS, &
JACKET, PREFERABLY NEOPRENE.
Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE
REUSE.
Supplemental Safety and Health
INTAKE OF HIGHLY CONTAMINATED WATER COULD RESULT IN SERIOUS HEALTH
PROBLEMS.

Boiling Pt:B.P. Text:148F
Melt/Freeze Pt:M.P/F.P Text:-144F
Vapor Pres:96
Vapor Density:1.105
Spec Gravity:0.792
Evaporation Rate & Reference:(BU AC =1): 4.6
Solubility in Water:COMPLETE
Appearance and Odor:CLEAR COLORLESS LIQUID W/SLIGHT ALCOHOL ODOR.
Percent Volatiles by Volume:100%

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS, ACIDS, & BASES.
Stability Condition to Avoid:IGNITION SOURCES & OPEN FLAME.
Hazardous Decomposition Products:FORMALDEHYDE, CO, TOXIC GASES, VAPORS,
& UNBURNED METHANOL.

Waste Disposal Methods:WASTE MATERIALS MUST BE DISPOSED OF IN
ACCORDANCE W/MUNICIPAL, STATE, PROVINCIAL, & FEDERAL REGULATIONS.
UN1230.

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This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.